WebBridgehead nitrogen (or ring-junction nitrogen) heterocycles are one of the most privileged scaffolds in synthetic chemistry and medicinal chemistry. For decades, transition metal-catalyzed C–H activation has provided straightforward access to bridgehead nitrogen heterocycles in an atom-economical manner. Pa 2024 Organic Chemistry Frontiers … WebN-C bond and (ii) an axis passing through the unsaturated bridgehead carbon so as to form equal angles with the three bridgehead bonds. In a similar fashion, for a bridgehead alkene, the definition of 0 has been the dihedral angle between the planes defined by the C:C bond and (i) an axis passing
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